For instance, if compiling with gcc and the option --stc=c++11, WIN32 is not defined.
See http://webcache.googleusercontent.com/search?q=cache:amvfgAUCdsgJ:sourceforge.net/p/mingw-w64/mailman/message/31850993/+&cd=4&hl=en&ct=clnk&gl=no
http://sourceforge.net/p/mingw-w64/mailman/message/31850993/